Nitration of Benzamide


2835-68-9. p-Aminobenzamide. Acetyl group can then be removed by acid-catalyzed hydrolysis to yield para-nitroaniline. QIKYZXDTTPVVAC-UHFFFAOYSA-N. 77722I6PAC. EC Number 201-851-2. 4-amino benzamide. NSC 36963.

Benzamide, 4-amino-4-Amino-benzamide. PubChem Substance ID 24891390. The Hofmann rearrangement is an important example of a rearrangement reaction that is discussed in most sophomore organic chemistry texts. MFCD00007999. 3-Nitroaniline, also known as meta-nitroaniline and m-nitroaniline, is a non-volatile stable solid commonly used as a raw material for dyes. CCRIS 6792.

The synthesis of 3-nitrobenzamide by nitration of benzamide and the subsequent Hofmann rearrangement can be carried out in two-and-a-half hours, making this a new and simple two-step reaction sequence for the organic laboratory. 4-Aminobenzamide, 98%.

A detailed mechanism illustrating nitration reactions involving nitric acid (HNO3) and sulfuric acid (H2SO4). p-Carbamoylaniline.

The mechanism involves protonation of the amide on oxygen followed by attack of water on the carbonyl carbon. UNII-77722I6PAC. EINECS 220-612-3. Molecular Weight 136.15 . Anthranilamide ≥98% Synonym: 2-AB, 2-Aminobenzamide, Anthranilic acid amide CAS Number 88-68-6. Yet very few … It can be synthesized by nitration of benzamide followed by the Hofmann rearrangement of the 3-nitrobenzamide previously formed.
SDS Certificate of Analysis (COA) FTNMR (PDF) Similar Products. Benzamide, p-amino-p-Aminobenzoic acid amide. Beilstein/REAXYS Number 508509 . Acetanilide which can be obtained by acetylation of aniline undergoes nitration at low temperature and yields highly the para-nitro products. Purchase; Safety & Documentation; … Linear Formula 2-(H 2 N)C 6 H 4 CONH 2.

Hydrolysis under acidic conditions requires strong acids such as sulfuric or hydrochloric, and temperatures of about \(100^\text{o}\) for several hours.

MDL number MFCD00007981.

CHEMBL332444. 4-Aminobenzamide. NSC 233920.
aminobenzamide …

Although the activating affection of the amino group can be reduced, the acetyl derivative remains an ortho/para-orientation and activating substituent. NACRES NA.22 .